基本信息

职称：讲师

所在系室：能源与动力工程

联系方式：maokeke@ahut.edu.cn

通信地址：安徽工业大学能源与环境学院，243002

教育背景

2018.1—2019.12 美国内布拉斯加大学林肯分校，化学专业 访问博士后

2009.9—2015.6   中国科学技术大学，材料物理化学专业 博士研究生

2005.9—2009.6  河南师范大学，物理学专业 大学本科

研究方向

基于第一性原理设计新型纳米催化剂，以及催化反应机制的理论模拟与研究

科研项目

1. 主持人. 衬底调控二维材料负载单原子催化剂催化性能的理论研究（21803002），国家自然科学基金青年基金项目，2019/01-2021/12.

2. 主持人. 石墨烯基NH3-SCR低温脱硝催化的密度泛函理论研究（KJ2016A090）, 安徽教育厅高校自然科学研究项目，2016/01-2017/12.

3. 参与人. 改性Fe2O3/AC催化剂烧结烟气低温SCR脱硝活性优化机理（51676001），国家自然科学基金面上项目，2017/01-2019/12.

4. 参与人.衬底调控石墨烯与类石墨烯二维单层材料表面化学活性的理论研究（B030204），国家自然科学基金面上项，2016/01-2018/12.

5. 参与人. 中组部青年拔尖人才支持计划（支持人武晓君180万），已结题

6. 参与人. 杂化调控的石墨烯自旋电子器件的原理、设计与稳定性的理论研究（51172223），国家自然科学基金面上项目，2012/01-2015/12.

7. 参与人. 单分子体系的非弹性电子遂穿谱的理论研究（11074235），国家自然科学基金面上项目， 2011/01-2013/12.

教研项目

1. 材料物理化学精品线下课程 安徽省高等学校省级质量工程（2020kfkc115）

   代表性论文专著

2. Keke Mao#, Wei Zhang#, Jun Dai and Xiao Cheng Zeng,* “Carbon fragments as highly active metal-free catalysts for the oxygen reduction reaction: a mechanistic study” Nanoscale, 2019, 11, 19422–19428

3. Keke Mao, Xiaojun Wu, * and Jinlong Yang. Enhanced Selective Oxidation of h-BN Nanosheet through Substrate Mediated Localized Charge Effect. Physical Chemistry Chemical Physics, 2017, 19, 4435-4439.

4. Keke Mao, Wenhua Zhang*, Yong Pei, Xiao Cheng Zeng, Xiaojun Wu* and Jinlong Yang. A Theoretical Study of Single-Atom Catalysis of CO Oxidation Using Au Embedded 2D h-BN Monolayer: A CO-Promoted O2 Activation. Scientific Reports 2015, 4:5441.

5. Jun Ma#,  Keke Mao#(共同第一作者), Jingxiang Low, Zihao Wang, Dawei Xi, Wenqing Zhang, Huanxin Ju, Zeming Qi, Ran Long, Xiaojun Wu, Li Song  Yujie Xiong*. Efficient Photoelectrochemical Conversion of Methane into Ethylene Glycol by WO3 Nanobar Arrays. Angew. Chem. Int. Ed. 2021, DOI: 10.1002/anie.202101701

6. Wenbin Jiang#, Jingxiang Low#, Keke Mao#(共同第一作者), Delong Duan, Shuangming Chen, Wei Liu, Chih-Wen Pao, Jun Ma, Shuaikang Sang, Chang Shu, Xiaoyi Zhan, Zeming Qi, Hui Zhang, Zhi Liu, Xiaojun Wu, Ran Long*, Li Song, and Yujie Xiong* “Pd-Modified ZnO–Au Enabling Alkoxy Intermediates Formation and Dehydrogenation for Photocatalytic Conversion of Methane to Ethylene” J. Am. Chem. Soc. 2021, 143, 1, 269–278

7. Wenqing Zhang, Keke Mao, Jingxiang Low, Hengjie Liu, Yanan Bo, Jun Ma, Qiaoxi Liu, Yawen Jiang, Jiuzhong Yang, Yang Pan, Zeming Qi, Ran Long*, Li Song, and Yujie Xiong* “Working-in-tandem mechanism of multi-dopants in enhancing electrocatalytic nitrogen reduction reaction performance of carbon-based materials” Nano Res. 2021, DOI: 10.1007/s12274-021-3315-1

8. Xiaonong Wang, Chao Gao, Jingxiang Low, Keke Mao, Delong Duan, Shuangming Chen, Run Ye, Yunrui Qiu, Jun Ma, Xusheng Zheng, Ran Long,⇑, Xiaojun Wu, Li Song, Junfa Zhu, Yujie Xiong “Efficient photoelectrochemical CO2 conversion for selective acetic acid production” Science Bulletin. 2021, DOI: 10.1016/j.scib.2021.04.004

9. Yu Guo, Qisheng Wu, Yunhai Li, Ning Lu, Keke Mao, Yizhen Bai, Jijun Zhao,* Jinlan Wang* and  Xiao Cheng Zeng* "Copper(I) sulfide: a two-dimensional semiconductor with superior oxidation resistance and high carrier mobility," Nanoscale Horiz. 2019, 4, 223-230.

10. Yu Guo, Liang Ma, Keke Mao, Minggang Ju, Yizhen Bai, Jijun Zhao* and Xiao Cheng Zeng,* “Eighteen functional monolayer metal oxides: wide bandgap semiconductors with superior oxidation resistance and ultrahigh carrier mobility,” Nanoscale Horiz. 2019, 4, 592-600.

11. Yang You#, , Hao Huang# , Keke Mao# ( 共同第一作者), Song Xia, Di Wu, Canyu Hu, Chao Gao, Panyiming Liu1, Ran Long,*, Xiaojun Wu, Yujie Xiong,* “Tandem nanocatalyst design: putting two step-reaction sites into one location towards enhanced hydrogen transfer reactions” Science China Materials. 2019, 62(9), 1297-1305.

12. Wei Zhang#, Keke Mao# ( 共同第一作者) , Xiao Cheng Zeng* “B Doped MnN4G Nanosheets as Bifunctional Electrocatalysts for Both Oxygen Reduction and Oxygen Evolution Reactions” ACS Sustainable Chem. Eng. 2019, 7, 18711−18717

13. Yunlan Sun, Rong Sun, Baozhong Zhu*. Keke Mao, Yuxin Wu. Thermal reaction mechanisms of nano- and micro-scale aluminum powders in carbon dioxide at low heating rate. Journal of Thermal Analysis and Calorimetry, 2016, 124(3), 1727-1734.

14. Liang Ma, Chengming Wang, Bao Yu Xia, Keke Mao, Jiawei He, Xiaojun Wu, Yujie Xiong,* and Xiong Wen (David) Lou*. Platinum Multicubes Prepared by Ni2+-Mediated Shape Evolution Exhibit High Electrocatalytic Activity for Oxygen Reduction Angew. Chem. Int. Ed. 2015, 54(19), 5666.

15. Ran Long, Zhoulv Rao, Keke Mao, Yu Li, Chao Zhang, Qiliang Liu, Chengming Wang, Zhi-Yuan Li, Xiaojun Wu, and Yujie Xiong*. Efficient Coupling of Solar Energy to Catalytic Hydrogenation by Using Well-Designed Palladium Nanostructures. Angew. Chem. Int. Ed. 2015, 54(8), 2425-2430.

16. Ran Long#, Keke Mao#(共同第一作者), Ming Gong, Shan Zhou, Jiahua Hu, Min Zhi, Yang You, Song Bai, Jun Jiang, Qun Zhang,* Xiaojun Wu*, and Yujie Xiong*. Tunable Oxygen Activation for Catalytic Organic Oxidation: Schottky Junction versus Plasmonic Effects. Angew. Chem. Int. Ed. 2014, 53, 3205 –3209.

17. Ran Long, Keke Mao, Xiaodong Ye, Wensheng Yan, Yaobing Huang , Jianyong Wang , Yao Fu , Xisheng Wang , Xiaojun Wu , Yi Xie, and Yujie Xiong*. Surface facet of palladium nanocrystals: a key parameter to the activation of molecular oxygen for organic catalysis and cancer treatment. J. Am. Chem. Soc. 2013, 135(8), 3200-3207.